1359874-38-6

Basic information

• Product Name: benzyl allyl(p-tolyl)carbamate
• Synonyms: benzyl allyl(p-tolyl)carbamate
• CAS NO: 1359874-38-6
• Molecular Weight: 281.354
• Mol File: 1359874-38-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: benzyl allyl(p-tolyl)carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl allyl(p-tolyl)carbamate(1359874-38-6)
• EPA Substance Registry System: benzyl allyl(p-tolyl)carbamate(1359874-38-6)

Safety Data

• Hazardous Substances Data: 1359874-38-6(Hazardous Substances Data)

Upstream product

• 7625-64-1 p-tolyl-carbamic acid benzyl ester 
• 106-95-6 allyl bromide 
• 106-49-0 p-toluidine 
• 501-53-1 benzyl chloroformate 

Downstream Products

• 1428098-55-8 C₂₂H₁₉F₉INO₂ 
• 1428098-44-5 benzyl 5-chloro-4,4,5,5-tetrafluoro-2-iodopentyl(p-tolyl)carbamate 
• 1428098-75-2 5-(2,2,3,3,4,4,5,5,5-nonafluoropentyl)-3-p-tolyloxazolidin-2-one 
• 1428098-65-0 5-(3-chloro-2,2,3,3-tetrafluoropropyl)-3-p-tolyloxazolidin-2-one 
• 1359874-55-7 5-[(N-(4-methylphenyl)-benzyloxycarbonylamino)methyl]-4,5-dihydro-isoxazole-3-carboxylic acid ethyl ester 
• 24601-01-2 1-(4-methylphenyl)pyrrole-2-carboxylic acid ethyl ester 

Relevant articles and documents

Microwave-assisted expeditious synthesis of 5-fluoroalkyl-3-(aryl/alkyl)- oxazolidin-2-ones

An efficient and convenient protocol for synthesis of 5-fluoroalkyl-3- (aryl/alkyl)-oxazolidin-2-ones is described. The reaction of allyl (aryl/alkyl) carbamates with fluoroalkyl iodide initiated by sodium dithionite in aqueous acetonitrile resulted in adducts that undergoes a cyclization assisted by microwave irradiation to form 5-fluoroalkyl-3-(aryl/alkyl)-oxazolidin-2-ones with high yields. It was also found that the products can be more efficiently formed via an AIBN-initiated one-pot addition-cyclization sequence from benzyl allyl(aryl/alkyl) carbamates and fluoroalkyl iodide.