136000-74-3Relevant articles and documents
ORGANOPHOSPHORUS CHEMISTRY, 21. THE BEHAVIOUR OF 1-DICYANOMETHYLENE-ACENAPHTHEN-2-ONE AND 1-DICYANOMETHYLENE-3-INDANONE TOWARD ATTACK BY ALKYL PHOSPHITES
Mahran, Mohamed R.,Abdou, Wafaa M.,Ganoub, Neven A. F.,Abdallah, Hisham A.
, p. 217 - 225 (2007/10/02)
Trialkylphosphites (1a-c) and dialkyl phosphonates (11a-c) attacked 1-dicyanomethylene-acenaphthen-2-one (9) at the α-carbon atom with respect to the nitrile group, to give phosphonate adducts 13a-c and 14a-c, respectively.The reaction proceeded according to 1:2 addition.On the other hand, 1 reacts with 1-dicyanomethylene-3-indanone (10) to give the respective O-alkylated products 17, while 11 attacked 10 at the β-carbon atom with respect to the nitrile group to give the corresponding phosphonates 18.Structures of the new compounds were confirmed on the basis of elemental analyses and spectral studies. Key words: α,β-Unsaturated nitriles; phosphorylation; C-alkylation, O-alkylation.