136003-07-1

Basic information

• Product Name: 3-Oxo-butyric acid (1S,2R,3S,5R)-6,6-dimethyl-2-phenyl-bicyclo[3.1.1]hept-3-yl ester
• Synonyms: 3-Oxo-butyric acid (1S,2R,3S,5R)-6,6-dimethyl-2-phenyl-bicyclo[3.1.1]hept-3-yl ester
• CAS NO: 136003-07-1
• Molecular Weight: 300.398
• Mol File: 136003-07-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Oxo-butyric acid (1S,2R,3S,5R)-6,6-dimethyl-2-phenyl-bicyclo[3.1.1]hept-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Oxo-butyric acid (1S,2R,3S,5R)-6,6-dimethyl-2-phenyl-bicyclo[3.1.1]hept-3-yl ester(136003-07-1)
• EPA Substance Registry System: 3-Oxo-butyric acid (1S,2R,3S,5R)-6,6-dimethyl-2-phenyl-bicyclo[3.1.1]hept-3-yl ester(136003-07-1)

Safety Data

• Hazardous Substances Data: 136003-07-1(Hazardous Substances Data)

Upstream product

• 15506-53-3 cyclobutane-1,3-dione 
• 124355-75-5 (+)-2-phenylapoisopinocampheol 
• 591-51-5 phenyllithium 
• 124355-71-1 (-)-2-phenylapopinene 
• 124355-70-0 (+)-2-phenylnopinol 
• 38651-65-9 (1R,5S)-(+)-nopinone 

Downstream Products

• 136002-87-4 3-Hydroxy-butyric acid (1S,2R,3S,5R)-6,6-dimethyl-2-phenyl-bicyclo[3.1.1]hept-3-yl ester 

Relevant articles and documents

New Chiral Auxiliaries Derived from β-Pinene: Their Use in the Asymmetric Reduction of β-Keto-Esters

3-Ketobutyrates 6, derived from chiral auxiliary alcohols 5 - themselves efficiently prepared from β-pinene 4 - were reduced with zinc borohydride, giving 3-hydroxybutyrates 7 with 2-70percent de, depending on the nature of aryl group in alcohols 5.