136068-03-6Relevant articles and documents
Generation of β-keto radicals from cyclopropanols catalyzed by AgNO3
Chiba, Shunsuke,Cao, Zhengyan,El Bialy, Serry Atta Atta,Narasaka, Koichi
, p. 18 - 19 (2007/10/03)
Various β-keto radicals are generated from cyclopropanols by treatment with a catalytic amount of AgNO3 and (NH4) 2S2O8 as a reoxidant in the presence of pyridine. Thus, generated β-keto radicals react with alkenes to yield addition products. Copyright
Generation of β-Keto Radicals from Cyclopropanol Derivatives by the Use of Manganese(III) 2-Pyridinecarboxylate as an Oxidant and Their Reactions with Olefins
Iwasawa, Nobuharu,Hayakawa, Satoshi,Isobe, Koichi,Narasaka, Koichi
, p. 1193 - 1196 (2007/10/02)
Various β-keto radicals are generated from cyclopropanol derivates such as 1- or 2-substituted cyclopropanols and a cyclopropanone hemiacetal by the use of manganese(III) 2-pyridinecarboxylate, and their reactions with electron-rich olefins give cross-addition products in good yields.