1360927-91-8

Basic information

• Product Name: Mo(((C₆H₅)2P)3CH)(CO)3(C₂H₅CN)
• CAS NO: 1360927-91-8
• Molecular Weight: 803.625
• Mol File: 1360927-91-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Mo(((C₆H₅)2P)3CH)(CO)3(C₂H₅CN)(CAS DataBase Reference)
• NIST Chemistry Reference: Mo(((C₆H₅)2P)3CH)(CO)3(C₂H₅CN)(1360927-91-8)
• EPA Substance Registry System: Mo(((C₆H₅)2P)3CH)(CO)3(C₂H₅CN)(1360927-91-8)

Safety Data

• Hazardous Substances Data: 1360927-91-8(Hazardous Substances Data)

Upstream product

• 103933-26-2 tris(propionitrile)tricarbonylmolybdenum⁽⁰⁾ 
• 28926-65-0 Tris(diphenylphosphino)methan 

Relevant articles and documents

Synthesis and characterization of molybdenum and tungsten complexes containing tris(diphenylphosphino)methane (tdppm)

Reaction of tris(diphenylphosphino)methane, (Ph2P)3CH (tdppm) with 1 equivalent of M(CO)3(EtCN)3 (M = Mo 1a, M = W 1b) affords [Mo{η2-(Ph2P)3CH}(CO) 3(EtCN)] 2a and [W{η2-(Ph2P) 3CH}(CO)3(EtCN)] 2b, respectively. Single crystal structure determinations were performed for complexes 2a and 2b. Both structures adopt a distorted octahedral geometry about Mo and W atoms, with one CO and EtCN group occupying an axial position, while the phosphine ligand and two CO ligands occupy the equatorial positions. To our knowledge this is the first structurally-characterized W complex containing the tdppm ligand.