1361146-95-3

Basic information

• Product Name: (E)-tert-butyl((2-methylpenta-2,4-dien-1-yl)oxy)diphenylsilane
• Synonyms: (E)-tert-butyl((2-methylpenta-2,4-dien-1-yl)oxy)diphenylsilane
• CAS NO: 1361146-95-3
• Molecular Weight: 336.549
• Mol File: 1361146-95-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-tert-butyl((2-methylpenta-2,4-dien-1-yl)oxy)diphenylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-tert-butyl((2-methylpenta-2,4-dien-1-yl)oxy)diphenylsilane(1361146-95-3)
• EPA Substance Registry System: (E)-tert-butyl((2-methylpenta-2,4-dien-1-yl)oxy)diphenylsilane(1361146-95-3)

Safety Data

• Hazardous Substances Data: 1361146-95-3(Hazardous Substances Data)

Upstream product

• 122057-55-0 2-methyl-2,4-pentadienoic acid methyl ester 
• 75088-96-9 (2E)-ethyl 2-methylpenta-2,4-dienoate 
• 1572-71-0 (E)-2-methylpenta-2,4-dien-1-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 663949-46-0 C₂₅H₃₄O₃Si 
• 1361146-56-6 (S,E)-5-((tert-butyldiphenylsilyl)oxy)-4-methylpent-3-ene-1,2-diol 
• 1422278-51-0 (1S,2S,3R,4R)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-2-methyl-3-vinylcyclohexane-1,4-diol 
• 1422278-52-1 (1R,2R,3S,4S)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-2-methyl-3-vinylcyclohexane-1,4-diol 

Relevant articles and documents

Synthesis of Two Key Fragments of the Complex Polyhalogenated Marine Meroterpenoid Azamerone

A concise route toward two advanced fragments in the context of the total synthesis of the unique natural product azamerone is reported. Key synthetic features include the enantioselective synthesis of an epoxysilane and its Lewis-acid-induced cyclization and the installation of the pyridazine ring via a formylation/condensation sequence. This route provides strategic insights into the chemistry of phthalazinediols, facilitating synthetic approaches toward this class of natural products.