13613-74-6

Basic information

• Product Name: SUCCINIC ACID, [1,4-14C]
• Synonyms: SUCCINIC ACID, [1,4-14C];Succinic acid-carboxy-14C
• CAS NO: 13613-74-6
• Molecular Formula: C4H6O4
• Molecular Weight: 122.12
• Mol File: 13613-74-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /crystalline
• Storage Temp.: 2-8°C
• CAS DataBase Reference: SUCCINIC ACID, [1,4-14C](CAS DataBase Reference)
• NIST Chemistry Reference: SUCCINIC ACID, [1,4-14C](13613-74-6)
• EPA Substance Registry System: SUCCINIC ACID, [1,4-14C](13613-74-6)

Safety Data

• Hazard Codes: Xi,R
• Statements: 37/38-41
• Safety Statements: 26-39
• RIDADR: UN 2910 7
• WGK Germany: 3
• Hazardous Substances Data: 13613-74-6(Hazardous Substances Data)

Upstream product

• 7732-18-5 water 
• 42331-58-8 [14C₂-1,4]succinonitrile 

Relevant articles and documents

Synthesis of (14C6-3,4,7,8,11,12)-(1E,5E,9E)- cyclododeca-1,5,9-triene

Trimerization of butadiene in the presence of Ni(0) affords (1E,5E,9E)-cyclododeca-1,5,9-triene 1 (ttt-CDT), (1E,5E,9Z)-cyclododeca-1,5,9- triene 2 (ttc-CDT), and other isomers/oligomers. After optimization of reaction conditions, [14C6-3,4,7,8,11,12]-ttt-CDT 1 was synthesized efficiently either by homogenous or heterogeneous Ni(0) catalytic trimerization of [1,4-14C2]butadiene 10, in 60-82% yield. Depending on the exact reaction conditions employed, the yields and ratio of 1/2 ranged from (59-90%) / (41-10%). The all-trans isomer was conveniently isolated via Ag +-mediated reversed-phase HPLC. The important intermediate [1,4- 14C2]-1,3-butadiene 10 was prepared from potassium [ 14C]cyanide and 1,2-dibromoethane 3 as starting materials, in seven steps with a 57% yield. The total radioactive yield of [14C 6-3,4,7,8,11,12]-ttt-CDT 1 is 30% from [14C]KCN. Copyright