136158-37-7Relevant articles and documents
Synthesis of optically active γ-trimethylsilyl-β,γ-epoxy tertiary alcohols by the diastereoselective addition reaction of β-trimethylsilyl-α, β-epoxyketones with Grignard reagents
Okamoto, Sentaro,Tsujiyama, Hiromi,Yoshino, Toshiharu,Sato, Fumie
, p. 5789 - 5792 (2007/10/02)
The reaction of β-trimethylsilyl-α,β-epoxyketones, readily prepared in a chiral form by using the Sharpless kinetic resolution of γ-trimethylsilyl secondary allylic alcohols as a key reaction, with Grignard reagents proceeds highly diastereoselectivity to