1362860-36-3Relevant articles and documents
Well-Defined and Robust Rhodium Catalysts for the Hydroacylation of Terminal and Internal Alkenes
Prades, Amparo,Fernández, Maitane,Pike, Sebastian D.,Willis, Michael C.,Weller, Andrew S.
supporting information, p. 8520 - 8524 (2015/11/27)
A Rh-catalyst system based on the asymmetric ligand tBu2PCH2P(o-C6H4OMe)2 is reported that allows for the hydroacylation of challenging internal alkenes with β-substituted aldehydes. Mechanistic studies point to the stabilizing role of both excess alkene and the OMe-group.