136287-51-9Relevant articles and documents
REACTION OF DICHLOROCARBENE WITH SPIROHEPTA-4,6-DIENE
Molchanov, A. P.,Vorob'eva, I. S.,Koroleva, L. B.,Kostikov, R. R.
, p. 2186 - 2189 (2007/10/02)
Dichlorocarbene adds to spirohept-4,6-diene with the formation of 6,6-dichlorospiro(bicyclohex-2-ene-4,1'-cyclopropane).When heated the latter undergoes isomerization to 3-(2-chloroethyl)chlorobenzene, and in the presence of nucleophiles (alcohols, amines) it is converted into 3-(2-alkoxyethyl)chlorobenzenes and N-substituted 3-(2-aminoethyl)chlorobenzenes respectively.
