136301-33-2

Basic information

• Product Name: bis(benzenethiolato)(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II)
• CAS NO: 136301-33-2
• Molecular Weight: 644.192
• Mol File: 136301-33-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(benzenethiolato)(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II)(CAS DataBase Reference)
• NIST Chemistry Reference: bis(benzenethiolato)(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II)(136301-33-2)
• EPA Substance Registry System: bis(benzenethiolato)(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II)(136301-33-2)

Safety Data

• Hazardous Substances Data: 136301-33-2(Hazardous Substances Data)

Upstream product

• 4733-39-5 Bathocuproine 
• 5970-45-6 zinc(II) acetate dihydrate 
• 108-98-5 thiophenol 

Relevant articles and documents

Structural dependence of the luminescence from bis(substituted benzenethiolato)(2,9-dimethyl-1,10-phenanthroline)zinc(II) complexes

Changes in luminescence spectra and lifetimes of crystalline samples of the title compounds at 77 K are correlated with phase changes of the solids. The ease of conversion among phases is a general property of this class of materials. For bis(benzene-thiolato)(2,9-dimethyl-1,10-phenanthroline)zinc(II) complete structure determinations were made of both phases. The attendant changes of the optical properties are ascribed to rotation of the planes of the two thiol rings on a single zinc ion from an approximately perpendicular to a nearly face-to-face conformation as the slowly heated crystal undergoes the phase change. The relevance of these results to the problem of charge separation in solids is discussed.