136409-28-4

Basic information

• Product Name: N-<1-(4-Chlorphenyl)-2-phenylvinyl>iminotriphenylphosphoran
• Synonyms: N-<1-(4-Chlorphenyl)-2-phenylvinyl>iminotriphenylphosphoran
• CAS NO: 136409-28-4
• Molecular Weight: 489.984
• Mol File: 136409-28-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-<1-(4-Chlorphenyl)-2-phenylvinyl>iminotriphenylphosphoran(CAS DataBase Reference)
• NIST Chemistry Reference: N-<1-(4-Chlorphenyl)-2-phenylvinyl>iminotriphenylphosphoran(136409-28-4)
• EPA Substance Registry System: N-<1-(4-Chlorphenyl)-2-phenylvinyl>iminotriphenylphosphoran(136409-28-4)

Safety Data

• Hazardous Substances Data: 136409-28-4(Hazardous Substances Data)

Upstream product

• 623-03-0 4-Cyanochlorobenzene 
• 1243-97-6 benzyltriphenylphosphonium iodide 

Downstream Products

• 136409-42-2 4-(4-Chlorphenyl)-2-(diphenylmethylen)-6,6-bis(4-methoxyphenyl)-5-phenyl-3,6-dihydro-2H-1,3-thiazin 
• 136409-40-0 3,6-Bis(4-chlorphenyl)-2-(diphenylmethylen)-5-phenyl-2,3-dihydro-4(1H)-pyrimidon 
• 136409-35-3 N-<1-(4-Chlorphenyl)-2-phenylvinyl>diphenylacetamid 
• 136409-32-0 3-(4-Chlorphenyl)-1-(diphenylmethyl)isochinolin 
• 136409-30-8 4-(4-Chlorphenyl)-1,1,5-triphenyl-3-(triphenylphosphonio)-3-aza-1,4-pentadien-2-olat 
• 136409-39-7 6-(4-Chlorphenyl)-2-(diphenylmethylen)-3,3,5-triphenyl-2,5-dihydro-4(3H)-pyridinon 
• 136409-37-5 4-(4-Chlorphenyl)-2,6-bis(diphenylmethylen)-5-phenyl-5,6-dihydro-2H-1,3-oxazin 

Relevant articles and documents

N-Vinylketenimines

The title compounds 5 are generated in situ from N-vinyliminotriphenylphosphoranes 1 and ketenes 2 in a Wittig-type reaction.The phosphoranes are useful intermediates for the preparation of numerous heterocycles as illustrated by the formation of 1,3-oxazines 8, pyridinones 9, pyrimidinones 10 and 1,3-thiazines 11.Water adds readily to 5 to yield vinylacetamides 7, whereas thermal rearrangement gives rise to the isoquinoline 4 or the spiro system 6, respectively.Under very mild conditions, crystalline precursors (type 3) of the N-vinylketenimines, which still contain the triphenylphosphonio group, have been isolated.These react like the N-vinylketenimines generated in situ, giving however less byproducts. Key Words: Phosphorus ylides / Ketenes / Ketenimines