136411-67-1

Basic information

• Product Name: Oxirane, 2-(4-chlorophenyl)-2-(2-propenyl)-
• CAS NO: 136411-67-1
• Molecular Formula: C11H11ClO
• Molecular Weight: 194.661
• Mol File: 136411-67-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Oxirane, 2-(4-chlorophenyl)-2-(2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Oxirane, 2-(4-chlorophenyl)-2-(2-propenyl)-(136411-67-1)
• EPA Substance Registry System: Oxirane, 2-(4-chlorophenyl)-2-(2-propenyl)-(136411-67-1)

Safety Data

• Hazardous Substances Data: 136411-67-1(Hazardous Substances Data)

Upstream product

• 15336-98-8 diallyldibutyltin 
• 937-20-2 p-chlorophenacyl chloride 
• 24850-33-7 allyltributylstanane 
• 536-38-9 4-chlorobenzoylmethyl bromide 
• 106-95-6 allyl bromide 
• 1730-25-2 allylmagnesium bromide 

Downstream Products

• 67592-76-1 2-(4-chlorophenyl)pent-4-enal 

Relevant articles and documents

Formation of homoallylic bromohydrins in indium-mediated allylation reactions of phenacyl bromides in aqueous solution

A method is described for carrying out indium-mediated allylation reactions of phenacyl bromides in aqueous solution that form homoallylic bromohydrins. By employing subsequent base treatment, the homoallylic bromohydrins were converted to allylic epoxide

Multi-product classes obtained from allylation of α-halo ketones with allylzinc bromide

An efficient, one-pot synthesis procedure for the preparation of allylic epoxides, aldehydes and homoallylic alcohols (see scheme) has been described. The three industrial products were synthesized by the reaction of allylzinc bromide with a-halo ketones

The formation of cyclic ethers from diallyldibutyltin and halo ketones catalyzed by tetraethylammonium chloride

The cyclization reaction of diallyldibutyltin and α- or γ-halo ketones, especially chloro-substituted ketones, effectively proceeds in the presence of a catalytic amount of tetraethylammonium chloride, producing the corresponding 2-allyloxiranes or 2-ally