136457-23-3

Basic information

• Product Name: (1S,2S,3S,5R)-2-Bromo-3-hydroxy-7,7-diphenyl-bicyclo[3.2.0]heptan-6-one
• Synonyms: (1S,2S,3S,5R)-2-Bromo-3-hydroxy-7,7-diphenyl-bicyclo[3.2.0]heptan-6-one
• CAS NO: 136457-23-3
• Molecular Weight: 357.247
• Mol File: 136457-23-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (1S,2S,3S,5R)-2-Bromo-3-hydroxy-7,7-diphenyl-bicyclo[3.2.0]heptan-6-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S,3S,5R)-2-Bromo-3-hydroxy-7,7-diphenyl-bicyclo[3.2.0]heptan-6-one(136457-23-3)
• EPA Substance Registry System: (1S,2S,3S,5R)-2-Bromo-3-hydroxy-7,7-diphenyl-bicyclo[3.2.0]heptan-6-one(136457-23-3)

Safety Data

• Hazardous Substances Data: 136457-23-3(Hazardous Substances Data)

Upstream product

• 108-05-4 vinyl acetate 
• 92776-58-4 2-exo-bromo-3-endo-hydroxy-7,7-diphenylbicyclo<3.2.0>heptan-6-one 
• 5452-28-8 7,7-diphenylbicyclo<3.2.0>hept-2-en-6-one 
• 5452-28-8 7,7-diphenylbicyclo<3.2.0>hept-2-en-6-one 

Downstream Products

• 136376-30-2 Acetic acid (1R,2R,3R,5S)-2-bromo-6-oxo-7,7-diphenyl-bicyclo[3.2.0]hept-3-yl ester 
• 125261-43-0 6-t-Butyldimethylsilyloxy-3,3-diphenyltricyclo<3.2.0.0^1,4>heptan-2-one 
• 87274-28-0 methyl 4-oxo-7,7-diphenylhept-6-enoate 
• 109542-01-0 (E)-(R)-4-Hydroxy-7-methoxy-7,7-diphenyl-hept-5-enoic acid methyl ester 
• 87274-17-7 2,3-exo-epoxy-7,7-diphenylbicyclo<3.2.0>heptan-6-one 
• 125261-39-4 2exo-Bromo-3endo-t-butyldimethylsilyloxy-7,7-diphenylbicyclo<3.2.0>heptan-6-one 
• 87274-17-7 (1S,2R,4S,6R)-8,8-Diphenyl-3-oxa-tricyclo[4.2.0.0^2,4]octan-7-one 
• 125261-41-8 (+/-)-3-endo-Acetoxy-2-exo-bromo-7,7-diphenylbicyclo<3.2.0>heptan-6-one 
• 87274-17-7 2,3-endo-epoxy-7,7-diphenylbicyclo<3.2.0>heptan-6-one 

Relevant articles and documents

Chemoenzymatic Synthesis of Carbocyclic Oxetanocin-A Involving a Novel Photochemical Rearrangement

The anti-herpes agent carbocyclic oxetanocin-A (-)-2 has been prepared from the bicyclic ketone 3 via resolution of the bromohydrin 4 (using an enzyme-catalysed trans-esterification reaction) and a photocatalysed rearrangement of the epoxide (+)-6 to the

PHOTOLYSIS OF 2,3-EPOXY-7,7-DIPHENYLBICYCLOHEPTAN-6-ONES AND 2-exo, 3-exo-DIHYDROXY-7,7-DIPHENYLBICYCLOHEPTAN-6-ONE

Photolysis of 2,3-endo-epoxy-7,7-diphenylbicycloheptan-6-one ( 2 ) in methanol gave products ( 4 ), ( 8 ) derived from an oxacarbene intermediate and the products ( 5 ) - ( 7 ), ( 9 ) derived from an initially formed alkenylketene.Photolysis of the