1365640-09-0

Basic information

• Product Name: 4-allylphenyl propionate
• Synonyms: 4-allylphenyl propionate
• CAS NO: 1365640-09-0
• Molecular Weight: 190.242
• Mol File: 1365640-09-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-allylphenyl propionate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-allylphenyl propionate(1365640-09-0)
• EPA Substance Registry System: 4-allylphenyl propionate(1365640-09-0)

Safety Data

• Hazardous Substances Data: 1365640-09-0(Hazardous Substances Data)

Upstream product

• 501-92-8 4-(prop-2-enyl)phenol 
• 79-03-8 propionyl chloride 

Downstream Products

• 1209481-15-1 (E)-4-(1-propen-1-yl)phenyl propionate 

Relevant articles and documents

A general route for the stereoselective synthesis of (E)-(1-propenyl)phenyl esters by catalytic CC bond isomerization

A general and efficient procedure for the stereoselective synthesis of (E)-(1-propenyl)phenyl esters from readily accessible allylphenols has been developed. The process involves a two-step sequence consisting of the initial acylation of the allylphenols with an acid chloride, followed by catalytic CC bond isomerization in the resulting allylphenyl esters. The latter step was performed in methanol at 80 °C using catalytic amounts (0.5 mol %) of the commercially available bis(allyl)-ruthenium(IV) dimer [{RuCl(μ-Cl) (η3:η3-C10H16)} 2] (C10H16=2,7-dimethylocta-2,6-diene-1,8-diyl) . Reactions proceeded in high yields (68-93%) and short times (4-9 h) with complete E-selectivity.