136616-39-2

Basic information

• Product Name: (R,S)-trans-1-((Benzyloxy)methyl)-2-phenylcyclopropane
• Synonyms: (R,S)-trans-1-((Benzyloxy)methyl)-2-phenylcyclopropane
• CAS NO: 136616-39-2
• Molecular Weight: 238.329
• Mol File: 136616-39-2.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (R,S)-trans-1-((Benzyloxy)methyl)-2-phenylcyclopropane(CAS DataBase Reference)
• NIST Chemistry Reference: (R,S)-trans-1-((Benzyloxy)methyl)-2-phenylcyclopropane(136616-39-2)
• EPA Substance Registry System: (R,S)-trans-1-((Benzyloxy)methyl)-2-phenylcyclopropane(136616-39-2)

Safety Data

• Hazardous Substances Data: 136616-39-2(Hazardous Substances Data)

Upstream product

• 75-47-8 iodoform 
• 165754-26-7 [3-(benzyloxy)prop-1-en-1-yl]benzene 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 100-44-7 benzyl chloride 
• 101306-31-4 benzyl cinnamyl ether 
• 14399-53-2 bis(iodomethyl)zinc 
• 75-11-6 diiodomethane 
• 98-80-6 phenylboronic acid 
• 69520-20-3 (E)-1-Phenyl-2-(phenylmethoxy)ethene 
• 593-71-5 Chloroiodomethane 
• 100-39-0 benzyl bromide 

Relevant articles and documents

Palladium-Catalyzed Suzuki-Type Cross-Couplings of lodocyclopropanes with Boronic Acids: Synthesis of trans-1,2-Dicyclopropyl Alkenes

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Cyclopropanation of alkenes with CH2I2/Et3Al by the phase-vanishing method based on fluorous phase screen

Phase-vanishing (PV) method using perfluorohexanes as a screen phase was applied to cyclopropanation reactions with CH2I2/Et2Zn and CH2I2/Et3Al. When Et3Al was used as a carbenoid generator, the reaction proceeded smoothly and desired cyclopropane derivatives were obtained in high yield. The PV cyclopropanation took 2 or 3 days to complete, however, reduction of reaction time by a factor of 2-3 was also achieved by vigorous stirring after the bottom CH2I2 layer disappeared.

New family of cyclopropanating reagents: Synthesis, reactivity, and stability studies of iodomethylzinc phenoxides

A valuable alternative to the traditional Simmons-Smith reagents is offered by the title compounds, as a result of their ease of preparation and high reactivities towards unfunctionalized olefins (see scheme).