136649-76-8Relevant articles and documents
Cobalt-Catalyzed Photochemical Carbonylation of Allylic Amines
Mori, Sadayuki,Matsuyoshi, Hiroaki,Kudo, Kiyoshi,Sugita, Nobuyuki
, p. 1397 - 1400 (2007/10/02)
Allylic amines are carbonylated at room temperature in the presence of cobalt catalysts under UV irradiation.With allylamine, 2-pyrrolidone, N,N'-diallylurea, and N-allyl-3-butenamide were obtained.The photochemical cleavage of C-N bond of amines coordinated to cobalt metals was suggested.