136661-37-5

Basic information

• Product Name: bis[4-(dimethylamino)-3-nitrophenyl]methanone
• Synonyms: bis[4-(dimethylamino)-3-nitrophenyl]methanone
• CAS NO: 136661-37-5
• Molecular Formula: C₁₇H₁₈N₄O₅
• Molecular Weight: 358.34862
• Mol File: 136661-37-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: bis[4-(dimethylamino)-3-nitrophenyl]methanone(CAS DataBase Reference)
• NIST Chemistry Reference: bis[4-(dimethylamino)-3-nitrophenyl]methanone(136661-37-5)
• EPA Substance Registry System: bis[4-(dimethylamino)-3-nitrophenyl]methanone(136661-37-5)

Safety Data

• HazardClass: IRRITANT
• Hazardous Substances Data: 136661-37-5(Hazardous Substances Data)

Upstream product

• 7498-65-9 4,4'-dichloro-3,3'-dinitrobenzophenone 
• 124-40-3 dimethyl amine 
• 90-94-8 bis(p-dimethylaminophenyl)methanone 
• 68-12-2 N,N-dimethyl-formamide 
• 7664-93-9 sulfuric acid 
• 101-61-1 4,4'-methylene-bis(N,N-dimethylaniline) 
• 90-98-2 4,4'-Dichlorobenzophenone 

Downstream Products

• 5340-23-8 3,3'-diamino-4,4'-bis-dimethylamino-benzophenone 

Relevant articles and documents

TRANSFORMATIONS OF 1,1,1-TRICHLORO-2,2-BIS(4-CHLOROPHENYL)ETHANE, 4,4'-DICHLOROBENZOPHENONE, AND THEIR NITRO DERIVATIVES IN A SODIUM HYDROXIDE-AMIDE SOLVENT MEDIUM

The reaction of 1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane with alkali in an amide solvent leads to dehydrochlorination of the substrate.In 1,1,1-trichloro-2,2-bis(3-nitro-4-chlorophenyl)ethane under the same conditions substitution of the chlorine atoms in the bridging group by dimethylamino groups, formed as a result of hydrolysis of the solvent, occurs after dehydrochlorination.In 1,1,1-trichloro-2,2-bis(3,5-dinitro-4-chlorophenyl)ethane the chlorine atoms of benzene ring are substituted by dimethylamino groups.In the presence of CuCl 4,4'-dichlorobenzophenone is converted into 4,4'-bis(dimethylamino)benzophenone. 3,3'-Dinitro-4,4'-dichlorobenzophenone reacts with the sodium hydroxide-amide solvent system with the formation of 3,3'-dinitro-4,4'-bis(dimethylamino)-benzophenone and 3,3'-dinitro-4-hydroxy-4'-dimethylaminobenzophenone, the ratio of which is determined by the reaction temperature.