136735-59-6Relevant articles and documents
Rhodium-catalyzed asymmetric synthesis of β-branched esters from allylic amines
Laffoon, Summer D.,Wu, Zhao,Hull, Kami L.
supporting information, p. 7814 - 7817 (2018/07/25)
Allylic amines are converted to chiral, β-branched esters under rhodium catalysis in the presence of alcohol nucleophiles. Allylic amines with aliphatic and aromatic vinylic substituents are converted to ester products with excellent enantioselectivities in all cases. Several alcohol nucleophiles have been utilized in the reaction including 1° and 2° derivatives.
Nucleophilic substitution versus electron transfer: 1. On the mechanism of electrophilic fluorinations
Differding, Edmond,Rueegg, Gabriela M.
, p. 3815 - 3818 (2007/10/02)
The reaction of a citronellic ester enolate with electrophilic fluorinating agents gives open chain fluorinated products only. The absence of rearranged fluorinated products in this system - a potential precursor to a 5-hexenyl-type radical clock - indica
