13677-74-2Relevant articles and documents
Biomimetic Total Synthesis of Santalin Y
Strych, Sebastian,Journot, Guillaume,Pemberton, Ryan P.,Wang, Selina C.,Tantillo, Dean J.,Trauner, Dirk
, p. 5079 - 5083 (2015)
A biomimetic total synthesis of santalin Y, a structurally complex but racemic natural product, is described. The key step is proposed to be a (3+2) cycloaddition of a benzylstyrene to a "vinylogous oxidopyrylium", which is followed by an intramolecular F
Selective deprotection of propargyl ethers using tetrathiomolybdate
Swamy,Ilankumaran, Palanichamy,Chandrasekaran, Srinivasan
, p. 513 - 514 (2007/10/03)
Benzyltriethylammonium tetrathiomolybdate, [PhCH2NEt3]2MoS4, 1 deprotects propargyl ethers of alcohols and phenols in a selective manner in high yields. Easily reducible groups like nitro, aldehyde, keto and allyl are not affected.
