136773-78-9Relevant articles and documents
Glycosylidene Carbenes Part 4 Synthesis of Spirocyclopropanes from Acetamidoglycosylidene-Derived Diazirines
Vasella, Andrea,Witzig, Christian,Husi, Rene
, p. 1362 - 1372 (2007/10/02)
The synthesis of the first glycosylidene-derived 2-acetamido-2-deoxydiazirine 4 from N-acetylglucosamine 6 is described.Thus, 6 was transformed into the 3-O-mesylglucopyranoside 9 by glycosidation with allyl alcohol, benzylidenation, and mesylation (Schem