13679-86-2 Usage
Description
FEMA 3759, also known as 5-Isopropenyl-2-methyl-2-vinyltetrahydrofuran, is a naturally occurring compound with a pungent, herbaceous, green, boldo-like camphoraceous, piney, terpene-like, and slightly cineol-like odor. It is a dehydrated linalool oxide and is used in various applications due to its unique scent and properties.
Uses
Used in Perfumery:
FEMA 3759 is used as a fragrance ingredient for its pungent, herbaceous-green, bold-like camphoraceous, piney, terpene-like, and slightly cineol-like odor. It adds a fresh and natural scent to perfumes, contributing to their overall appeal.
Used in Flavor Industry:
FEMA 3759 is used as a flavoring agent for its unique and complex aroma. It can be used to enhance the taste and smell of various food and beverage products, providing a refreshing and natural flavor profile.
Used in Aromatherapy:
FEMA 3759 is used as an essential oil in aromatherapy for its invigorating and refreshing properties. Its pungent and herbaceous scent can help promote relaxation, reduce stress, and improve overall well-being.
Used in Cosmetics:
FEMA 3759 is used as an additive in the cosmetics industry for its pleasant and natural scent. It can be incorporated into various cosmetic products, such as lotions, creams, and soaps, to provide a refreshing and uplifting experience for users.
Used in the Pharmaceutical Industry:
FEMA 3759 is used as a component in the development of pharmaceutical products due to its unique chemical properties. It can be used in the formulation of medications, particularly those targeting respiratory and musculoskeletal issues, due to its refreshing and invigorating properties.
Check Digit Verification of cas no
The CAS Registry Mumber 13679-86-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,6,7 and 9 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 13679-86:
(7*1)+(6*3)+(5*6)+(4*7)+(3*9)+(2*8)+(1*6)=132
132 % 10 = 2
So 13679-86-2 is a valid CAS Registry Number.
InChI:InChI=1/C10H16O/c1-5-10(4)7-6-9(11-10)8(2)3/h5,9H,1-2,6-7H2,3-4H3
13679-86-2Relevant articles and documents
CHLORATION ALLYLIQUE D'OLEFINES DE TYPE ISOPRENIQUE A L'AIDE DU CHLORURE DE SULFURYLE
Bulliard, Michel,Balme, Genevieve,Gore, Jacques
, p. 5767 - 5770 (1989)
Sulfuryl chloride is a convenient reagent for the allylic chlorination of olefins bearing an isopropenyl or isopropylidenyl moiety.The substitution occurs with good yields and with allylic rearrangement, giving in most cases a secondary chloride.
Simple synthesis of karahanaenone
Konstantinovic, S.,Bugarcic, Z.,Marjanovic, Lj.,Gojkovic, S.,Mihailovic, M. Lj.
, p. 1169 - 1170 (2007/10/03)
Karahanaenone 1 has been prepared from linalool 3. Linalool 3 is cyclized to the corresponding tetrahydrofuran-type cyclic ethers 4a-c on treatment with PhSeCl, N-bromosuccinimide, and 3-chloroperbenzoic acid, respectively. 4a-c on further treatment with various reagents, provide allylic cyclic ether 6 which is converted to 1 via 2.
Synthesis of Karahanaenone
Uneyama, Kenji,Date, Takasi,Torii, Sigeru
, p. 3160 - 3163 (2007/10/02)
Karahanaenone (1) has been prepared from dehydrolinalyl acetate.Electrochemical epoxidation of dehydrolinalyl acetate provided the corresponding epoxide 6a (75percent) which was converted to keto acetate 7a (82percent) by an electrogenerated acid-catalyzed rearrangement.Hydrogenation followed by alkaline hydrolysis gave 6-hydroxy-2,6-dimethyl-7-octen-3-one (7c) (86percent), which was subjected to thermal dehydration at 200 deg C to give 1 (85percent) via Claisen type rearrangement of the intermediate 2-methyl-2-ethenyl-5-propylidenetetrahydrofuran (2).An alternative route to 1 via thermolysis of the xanthate of 1-(5-ethenyl-5-methyl-2-tetrahydrofuranyl)-1-methylethanol (10b) is also described.
