136809-07-9Relevant articles and documents
A New Version of the Peterson Olefination
Bellassoued, Moncef,Ozanne, Nicolas
, p. 6582 - 6584 (1995)
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General, green, and scalable synthesis of imines from alcohols and amines by a mild and efficient copper-catalyzed aerobic oxidative reaction in open air at room temperature
Tian, Haiwen,Yu, Xiaochun,Li, Qiang,Wang, Jianxin,Xu, Qing
supporting information, p. 2671 - 2677,7 (2012/12/12)
A general, green, and scalable synthesis of the useful imines and a,b-unsaturated imines is successfully achieved by a low-loading and powerful, mild and efficient copper-catalyzed aerobic oxidative reaction of alcohols and amines in the open air at room temperature under base- and dehydrating reagent-free conditions. This practical reaction can use air as the economic and green oxidant, tolerates a wide range of substrates, can afford high yields of the target imines on a large scale, and produces water as the only by-product, and thus being the best imination method as yet using alcohols and amines directly.
PREPARATION OF (E)-α,β-UNSATURATED AROMATIC ALDEHYDES BY HIGH STEREOSELECTIVE OLEFINFORMYLATION.
Gaudemar, Marcel,Bellassoued, Moncef
, p. 349 - 352 (2007/10/02)
Treatment of acetaldehyde N-ter-butylimine by two equivalents of LDA, followed by trimethylsilyl chloride trapping affords the α,α-disilylated imine; the latter reacts with aromatic aldehydes producing α,β-ethylenic aldehydes in excellent yields and with very high stereoselectivity in favour of the E isomer.
