136809-43-3Relevant articles and documents
Synthesis and Absorption/Emission Spectroscopic Properties of Bis(phenylethynyl)benzenes and 9,10-Bis(phenylethynyl)anthracenes
Nakatsuji, Shin'ichi,Matsuda, Kosei,Uesugi, Yukiko,Nakashima, Kenichiro,Akiyama, Shuzo,Fabian, Walter
, p. 755 - 758 (2007/10/02)
A series of bis(phenylethynyl)benzenes 3 and 9,10-bis(phenylethynyl)anthracenes 4 was synthesized by bromination-dehydrobromination reaction or newly developed direct triple bond formation reaction from styrylstilbenes 1 or distyrylanthracenes 2.Subsequently systematic investigations were carried out on their absorption and fluorescence spectra, and their chemiluminescence properties.The following points are apparent; (a) a linear relationship between and Hammett's ?P of compounds 3 and 4 was observed, (b) a significant relationship between Stokes' shift of 4 and ?P was observed and (c) in the series of compounds 4 the electron-donating ability of the substituents has a pronounced effect on the chemiluminescence properties.