136869-44-8

Basic information

• Product Name: 2,5-Cyclohexadiene-1,4-dione, 2-(methoxymethyl)-3,5,6-trimethyl-
• CAS NO: 136869-44-8
• Molecular Formula: C11H14O3
• Molecular Weight: 194.23
• Mol File: 136869-44-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,5-Cyclohexadiene-1,4-dione, 2-(methoxymethyl)-3,5,6-trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-Cyclohexadiene-1,4-dione, 2-(methoxymethyl)-3,5,6-trimethyl-(136869-44-8)
• EPA Substance Registry System: 2,5-Cyclohexadiene-1,4-dione, 2-(methoxymethyl)-3,5,6-trimethyl-(136869-44-8)

Safety Data

• Hazardous Substances Data: 136869-44-8(Hazardous Substances Data)

Upstream product

• 117574-74-0 (2,5-dimethoxy-3,4,6-trimethylphenyl)methanol 
• 103808-42-0 2,5-dimethoxy-3,4,6-trimethylbenzaldehyde 
• 4537-09-1 1,4-dimethoxy-2,3,5-trimethyl-benzene 
• 54757-17-4 1-chloromethyl-2,5-dimethoxy-3,4,6-trimethyl-benzene 
• 144707-05-1 1,4-dimethoxy-2-methoxymethyl-3,5,6-trimethylbenzene 
• 147225-22-7 2-lithio-2-nitropropane 
• 140848-84-6 2-fluoromethyl-3,5,6-trimethyl-1,4-benzoquinone 

Relevant articles and documents

Diels-alder trapping of ortho-quinone methides. A new entry to substituted xanthene- 1,4-diones

Highly regioselective Diels-Alder reactions of a non-protected β-hydroxy quinone have been achieved after formation of chelated lithium alkoxides. In this report, we demonstrate on a model system, that the selectivity of reactions based on 1,3-dioxy-subst

Fluoride as leaving group in SRN1 reactions of a tetrasubstituted-1,4-benzoquinone

2-Fluoromethyl-3,5,6-trimethyl-1,4-benzoquinone was synthesized and its reactivity in SRN1 reactions compared to the reactivity of the chloro derivative previously described. This study reports the first examples of the displacement of the fluoride in SRN1 reactions involving a substitution at an sp3 carbon atom.