136912-24-8

Basic information

• Product Name: 2-Thiabicyclo[2.2.2]oct-5-ene, 3-(2-chlorophenyl)-, (1R,3S,4S)-rel-
• CAS NO: 136912-24-8
• Molecular Formula: C13H13ClS
• Molecular Weight: 236.765
• Mol File: 136912-24-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Thiabicyclo[2.2.2]oct-5-ene, 3-(2-chlorophenyl)-, (1R,3S,4S)-rel-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Thiabicyclo[2.2.2]oct-5-ene, 3-(2-chlorophenyl)-, (1R,3S,4S)-rel-(136912-24-8)
• EPA Substance Registry System: 2-Thiabicyclo[2.2.2]oct-5-ene, 3-(2-chlorophenyl)-, (1R,3S,4S)-rel-(136912-24-8)

Safety Data

• Hazardous Substances Data: 136912-24-8(Hazardous Substances Data)

Upstream product

• 89-98-5 2-chloro-benzaldehyde 
• 1165952-91-9 cyclohexa-1,3-diene 

Relevant articles and documents

Silicon-Assisted Synthesis of Thiocarbonyl Derivatives and Reactivity of Dienophilic Thioaldehydes

Treatment of bis(trimethylsilyl) sulfide with CoCl2 * 6 H2O in the presence of aldehydes affords the corresponding thiocarbonyl analogues which can be trapped to avoid polymerization.The sulfurization reaction also takes place in the presence of TfOSiMe3, in which case, besides thioaldehydes, thioketones may be obtained in satisfactory yields.When thioaldehydes are generated with the CoCl2 * 6 H2O method the Diels-Alder reaction with cyclohexadiene occurs with very high selectivity in favor of the endo isomer, whereas when the TfOSiMe3-based method is employed, the stereochemistry of the cycloadduct can be conveniently selected toward endo or exo by varying the molar ratio of the sulfurating agent.