13697-98-8

Basic information

• Product Name: 2-bromo-1-(dibromophosphino)cyclohexane
• Synonyms: 2-bromo-1-(dibromophosphino)cyclohexane
• CAS NO: 13697-98-8
• Molecular Weight: 352.831
• Mol File: 13697-98-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-bromo-1-(dibromophosphino)cyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-1-(dibromophosphino)cyclohexane(13697-98-8)
• EPA Substance Registry System: 2-bromo-1-(dibromophosphino)cyclohexane(13697-98-8)

Safety Data

• Hazardous Substances Data: 13697-98-8(Hazardous Substances Data)

Upstream product

• 110-83-8 cyclohexene 

Downstream Products

• 332402-27-4 dibromo(1-cyclohexenyl)phosphine 
• 67990-88-9 2-Cyclohex-1-enyl-benzo[1,3,2]dioxaphosphole 2-oxide 
• 38868-16-5 cyclohex-1-en-1-yl(diphenyl)phosphine oxide 
• 82201-23-8 (1-cyclohexenyl)diphenylphosphine 

Relevant articles and documents

Synthesis of trivalent phosphorus derivatives by light-induced dibromophosphination of akenes

Light-induced dibromophosphination of alkenes was studied. Dehydrobromination of the synthesized bromoalkylphosphonous dibromides gave the corresponding dibromophosphinoalkenes which were converted into alkenylphosphonous acids and their cyclic esters, benzo[1,3,2]dioxaphospholes.

STEREOCHEMICAL STUDIES-XXIX STEREOCHEMISTRY OF THE ADDITION OF PHOSPHOROUS TRIBROMIDE TO OLEFINS

The stereochemical course of PBr3 addition to a series of cycloolefins has been found to depend crucially on the olefinic structure and the reaction proceeds in highly stereoselective fashion either as trans-(cyclohexene) or as cis-(norbornene and related