136981-75-4

Basic information

• Product Name: (3R,5S)-4-acetyl-3,5-diphenylcyclohexanone
• Synonyms: (3R,5S)-4-acetyl-3,5-diphenylcyclohexanone
• CAS NO: 136981-75-4
• Molecular Weight: 292.378
• Mol File: 136981-75-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (3R,5S)-4-acetyl-3,5-diphenylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,5S)-4-acetyl-3,5-diphenylcyclohexanone(136981-75-4)
• EPA Substance Registry System: (3R,5S)-4-acetyl-3,5-diphenylcyclohexanone(136981-75-4)

Safety Data

• Hazardous Substances Data: 136981-75-4(Hazardous Substances Data)

Upstream product

• 73400-25-6 {(1E)-3-[(trimethylsilyl)oxy]buta-1,3-dien-1-yl}benzene 
• 1896-62-4 (E)-benzalacetone 
• 3102-33-8 trans-3-penten-2-one 
• 75513-43-8 (1E, 4E)-1-(dimethylamino)-5-phenylpenta-1, 4-dien-3-one 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 136819-90-4 3-Acetyl-6-styryl-2-pyranone 

Relevant articles and documents

Investigations on the Formation of 4-Aminobicyclo[2.2.2]octanones

Benzylidene acetone reacts with thiocyanates derived from secondary amines in a one-pot reaction to give 4-aminobicyclo[2.2.2]octan-2-ones. The reaction mixture was investigated for the presence of possible intermediates using GC-MS. These intermediates -

Cyclodimerization of α,β-unsaturated ketones catalyzed by lanthanoid tri-2-propoxides

α,β-unsaturated ketones are cyclodimerized by the catalysis of lanthanoid tri-2-propoxides into substituted cycohexanones in good yields. The catalytic activity of the lanthanoids is fairly superior to those of the sodium or aluminum propoxides.

Michael Addition of Acyclic Lithium 1,3-Dien-2-olates with α,β-Unsaturated Esters, Ketones, and Diesters

The Michael addition of lithium 1,3-dien-2-olates with α,β-unsaturated carbonyl compounds is described.With α,β-unsaturated esters the reaction was reversible even at -78 deg C, while kinetically controlled with α,β-unsaturated ketones or alkylidenemalona