137050-87-4

Basic information

• Product Name: (S)-N-(4-Nitrobenzyloxycarbonyl)-β-phenyl-β-alanine
• Synonyms: (S)-N-(4-Nitrobenzyloxycarbonyl)-β-phenyl-β-alanine
• CAS NO: 137050-87-4
• Molecular Weight: 344.324
• Mol File: 137050-87-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-N-(4-Nitrobenzyloxycarbonyl)-β-phenyl-β-alanine(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-N-(4-Nitrobenzyloxycarbonyl)-β-phenyl-β-alanine(137050-87-4)
• EPA Substance Registry System: (S)-N-(4-Nitrobenzyloxycarbonyl)-β-phenyl-β-alanine(137050-87-4)

Safety Data

• Hazardous Substances Data: 137050-87-4(Hazardous Substances Data)

Upstream product

• 135865-82-6 (S)-N-(4-Nitrobenzyloxycarbonyl)-1-phenyl-3-butenylamine 

Downstream Products

• 83649-47-2 (S)-(-)-β-Phenyl-β-alanine hydrochloride 

Relevant articles and documents

Carbohydrates as Chiral Templates: Diastereoselective Synthesis of N-Glycosyl-N-homoallylamines and and β-Amino Acids from Imines

Complexing properties and chirality of carbohydrates were utilized in diastereoselective reactions of O-pivaloylated N-galactosylimines with allylsilanes and -stannanes.With allyltrimethylsilane in the presence of SnCl4 imines 2 of aromatic and heteroaromatic aldehydes were converted to homoallylamines 3, giving ratios of diastereomers higher than 7:1.No addition products derived from α-anomeric aromatic imines were formed.Aliphatic homoallylamines 3 were synthesized by using allyltributylatannane in the presence of SnCl4.Both α- and β-anomeric aliphatic imines reacted with the allylstannane.They gave the same ratio of diastereomers and showed the same sense of asymmetric induction.