137190-14-8

Basic information

• Product Name: Benzaldehyde, 4-[1-[(trimethylsilyl)methyl]ethenyl]-
• CAS NO: 137190-14-8
• Molecular Formula: C13H18OSi
• Molecular Weight: 218.371
• Mol File: 137190-14-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 4-[1-[(trimethylsilyl)methyl]ethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 4-[1-[(trimethylsilyl)methyl]ethenyl]-(137190-14-8)
• EPA Substance Registry System: Benzaldehyde, 4-[1-[(trimethylsilyl)methyl]ethenyl]-(137190-14-8)

Safety Data

• Hazardous Substances Data: 137190-14-8(Hazardous Substances Data)

Upstream product

• 619-66-9 4-Carboxybenzaldehyde 
• 42228-16-0 methyl 4-(dimethoxymethyl)benzoate 
• 494205-57-1 2-(4-dimethoxymethyl-phenyl)-1,3-bis-trimethylsilanyl-propan-2-ol 
• 125405-22-3 2-trimethylstannyl-3-trimethylsilylpropene 
• 1122-91-4 4-bromo-benzaldehyde 

Relevant articles and documents

Asymmetric synthesis of chiral polymers by means of repetitive addition of allylsilane to aldehyde

Monomers having both allyltrimethylsilyl and formyl groups were prepared. Chiral (acyloxy)borane initiated the repetitive polyaddition of the monomers to give optically active polymers having main chain configurational chirality. Optical purity of the chiral polymer was evaluated by the analysis of the degradation product.

Synthesis of functionalized allylsilanes via palladium-catalyzed cross-coupling of 2-stannyl-3-silylpropene with organic halides

Allylsilanes bearing the various functionalities were prepared from the palladium-catalyzed cross-coupling reactions of 2-trimethylstannyl-3-trimethylsilylpropene with acid chlorides and with aryl halides.