137379-63-6Relevant articles and documents
Efficient Pd-catalyzed synthesis of 2-arylaminopyrimidines via microwave irradiation
Zhang, Henry Q.,Xia, Zhiren,Vasudevan, Anil,Djuric, Stevan W.
, p. 4881 - 4884 (2006)
An efficient method for the synthesis of 2-arylaminopyrimidines via microwave assisted, Pd-mediated amination of 2-chloropyrimidine is reported. This method is superior to the classical heating process, particularly when one of starting materials is a het
The Direct Rh(III)-Catalyzed C-H Amidation of Aniline Derivatives Using a Pyrimidine Directing Group: The Selective Solvent Controlled Synthesis of 1,2-Diaminobenzenes and Benzimidazoles
Chatani, Naoto,Khake, Shrikant M.
supporting information, p. 3655 - 3660 (2020/05/22)
The regioselective Rh(III)-catalyzed C-H amidation of aniline derivatives with dioxazolones as an amidating reagent with a pyrimidine as a directing group leading to the production of 1,2-diaminobenzene derivatives or benzimidazole derivatives is describe
Cu/ N, N′-Dibenzyloxalamide-Catalyzed N-Arylation of Heteroanilines
Chen, Zhixiang,Ma, Dawei
supporting information, p. 6874 - 6878 (2019/09/07)
N,N′-Dibenzyloxalamide (DBO) was identified as a powerful ligand for promoting Cu-catalyzed coupling of heteroanilines with (hetero)aryl halides. For (hetero)aryl chlorides, the coupling reaction occurred at 130 °C with 5 mol % CuBr and 10 mol % DBO. For
