1374014-95-5

Basic information

• Product Name: (Z)-7-hexadecenyl tosylate
• CAS NO: 1374014-95-5
• Molecular Weight: 394.619
• Mol File: 1374014-95-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-7-hexadecenyl tosylate(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-7-hexadecenyl tosylate(1374014-95-5)
• EPA Substance Registry System: (Z)-7-hexadecenyl tosylate(1374014-95-5)

Safety Data

• Hazardous Substances Data: 1374014-95-5(Hazardous Substances Data)

Upstream product

• 764-93-2 1-decyne 
• 65785-44-6 6-iodohexanol, tetrahydropyranyl ether 
• 28793-45-5 7-hexadecyn-1-ol tetrahydropyran-2-yl ether 
• 822-21-9 hexadec-7-yn-1-ol 

Downstream Products

• 1374015-12-9 (S,11E,19E)-11,19-octacosadiene-1,3-diol 1-PMB ether 
• 1374015-13-0 (S,11E,19E)-3-acetoxy11,19-octacosadiene-1ol 1-PMB ether 
• 1374015-02-7 (R,Z)-3-tert-butyldimethylsilyloxy-19-octacosen-11-yn-1-ol PMB ether 
• 1374015-16-3 (S,Z)-3-tert-butyldimethylsilyloxy-19-octacosen-11-yn-1-ol PMB ether 
• 1374015-04-9 (R,11E,19Z)-11,19-octacosadiene-1,3-diol 1-PMB ether 
• 1374015-18-5 (S,11E,19Z)-11,19-octacosadiene-1,3-diol 1-PMB ether 
• 1374015-05-0 (R,11E,19Z)-3-acetoxy11,19-octacosadiene-1ol 1-PMB ether 
• 1374015-19-6 (S,11E,19Z)-3-acetoxy11,19-octacosadiene-1ol 1-PMB ether 

Relevant articles and documents

Pheromone synthesis. Part 250: Determination of the stereostructure of CH503, a sex pheromone of male Drosophila melanogaster, as (3R,11Z,19Z)-3- acetoxy-11,19-octacosadien-1-ol by synthesis and chromatographic analysis of its eight isomers

All the eight stereoisomers of 3-acetoxy-11,19-octacosadien-1-ol (1), the male sex pheromone (CH503) of Drosophila melanogaster, were synthesized from two acetylenic starting materials and the enantiomers of 3,4-epoxy-1-butanol PMB ether. Complete separation of the eight isomers of 1 by reversed phase HPLC at -20 °C was achieved after their esterification with (1R,2R)-2-(2,3- anthracenedicarboximido)cyclohexanecarboxylic acid (27), and the natural CH503 was found to be (3R,11Z,19Z)-1.