13755-04-9

Basic information

• Product Name: Decahydro-4a,8a-butanonaphthalene
• Synonyms: [4.4.4]Propellane;Decahydro-4a,8a-butanonaphthalene
• CAS NO: 13755-04-9
• Molecular Weight: 0
• Mol File: 13755-04-9.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Decahydro-4a,8a-butanonaphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: Decahydro-4a,8a-butanonaphthalene(13755-04-9)
• EPA Substance Registry System: Decahydro-4a,8a-butanonaphthalene(13755-04-9)

Safety Data

• Hazardous Substances Data: 13755-04-9(Hazardous Substances Data)

Upstream product

• 88879-57-6 tricyclo<4.4.4.0>tetradecane-2,7-dione 
• 17878-59-0 cis-4a-Carbomethoxy-methyl-8a-<β-carbomethoxy-ethyl>-Δ^2.6-hexalin 
• 14813-87-7 3-Hydroxy-4-methoxycarbonyltricyclo<4.4.4.0>tetradecatrien-<3.8.12> 
• 17878-58-9 cis-4a-Carboxymethyl-8a-carbomethoxymethyl-Δ^2.6-hexalin 
• 15070-49-2 3-Oxo-tricyclo<4.4.4.0>tetradecadien-(8,12) 
• 15529-31-4 (1,4,5,8-tetrahydro-naphthalene-4a,8a-diyl)-bis-acetic acid anhydride 
• 20379-94-6 8-methoxytricyclo<6.2.2.0^1,6>dodec-6-ene-9-one 
• 36365-67-0 3,8-Dioxo-<4.4.4>propellane 
• 17820-68-7 <4.4.4>-Propellanon-(3) 
• 42245-86-3 bicyclo<4.4.0>dec-1(6)-ene-2,7-dione 
• 15405-73-9 cis-1,6-bis(methoxycarbonylmethyl)bicyclo<4.4.0>deca-3,8-diene 
• 85862-13-1 8-Methoxy-3-oxo-Δ^7,8-<4.4.4>propellane 

Downstream Products

• 1687-36-1 1,3,5,7-tetramethyladamantane 

Relevant articles and documents

An Efficient General Method for Synthesis of Propellane and 11-Methyl-propellane

A general method for the synthesis of propellane and 11-methyl-propellane is described.Thus the exo-alcohol (6) obtained by the addition of vinylmagnesiumbromide to the tricyclic enone (5) smoothly undergoes an Oxy-Cope rearrangement to the propellane derivative (8) which is transformed into the propellane.Similarly 11-methyl-propellane has been obtained from exo-alcohol (17).