1375536-67-6

Basic information

• Product Name: (E)-2-(4-(4-(tert-butyl)phenyl)but-3-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• Synonyms: (E)-2-(4-(4-(tert-butyl)phenyl)but-3-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS NO: 1375536-67-6
• Molecular Weight: 314.276
• Mol File: 1375536-67-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-2-(4-(4-(tert-butyl)phenyl)but-3-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(4-(4-(tert-butyl)phenyl)but-3-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1375536-67-6)
• EPA Substance Registry System: (E)-2-(4-(4-(tert-butyl)phenyl)but-3-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1375536-67-6)

Safety Data

• Hazardous Substances Data: 1375536-67-6(Hazardous Substances Data)

Upstream product

• 3972-65-4 1-bromo-4-tert-butylbenzene 
• 27798-45-4 1-allyl-4-(tert-butyl)benzene 
• 78782-17-9 4,4,5,5-tetramethyl-2-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane 
• 149169-92-6 (E)-1-(3-bromoprop-1-en-1-yl)-4-(tert-butyl)benzene 

Relevant articles and documents

Palladium-catalyzed oxidative allylation of bis[(pinacolato)boryl]methane: Synthesis of homoallylic boronic esters

A palladium-catalyzed oxidative allylation of bis[(pinacolato)boryl]methane to afford the corresponding homoallylic organoboronic esters with moderate to excellent yields is reported. This novel transformation provides an efficient strategy for the construction of homoallylic organoboronic esters in one step with a broad substrate scope. It is proposed that the palladium-catalyzed oxidative allylic C-H bond activation process may be involved in the catalytic cycle.