1377149-79-5Relevant articles and documents
Radical mechanism in the elimination of 2-arylsulfinyl esters
Latorre, Antonio,Lopez, Irakusne,Ramirez, Victoria,Rodriguez, Santiago,Izquierdo, Javier,Gonzalez, Florenci V.,Vicent, Cristian
, p. 5191 - 5197 (2012)
The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction was found to follow a homolytic cleavage mechanism as verified by electrospray ionization tandem mass spectrometry and experimental work. Rearranged sulfoxides are obtained as byproduct during the elimination reaction.