137934-95-3

Basic information

• Product Name: Cyclohexanone, 2-hydroxy-3-methoxy-
• CAS NO: 137934-95-3
• Molecular Formula: C7H12O3
• Molecular Weight: 144.17
• Mol File: 137934-95-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2-hydroxy-3-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2-hydroxy-3-methoxy-(137934-95-3)
• EPA Substance Registry System: Cyclohexanone, 2-hydroxy-3-methoxy-(137934-95-3)

Safety Data

• Hazardous Substances Data: 137934-95-3(Hazardous Substances Data)

Upstream product

• 460357-62-4 3-methoxy-1,2-cyclohexanediol 
• 72170-87-7 (+)-(2S)-N-[cyclohex-2-en-1-yliden]-2-(methoxymethyl)pyrrolidin-1-amine 
• 6705-49-3 7-oxabicyclo[4.1.0]heptan-2-one 
• 67-56-1 methanol 

Downstream Products

• 137934-97-5 Essigsaeure-(6-methoxy-cyclohexan-2-on-1-yl)-ester 
• 10316-66-2 2-hydroxy-2-cyclohexen-1-one 
• 137934-98-6 2-Hydroxy-6-methoxycyclohexanon 

Relevant articles and documents

An efficient protocol for the oxidative hydrolysis of ketone SAMP hydrazones employing SeO2 and H2O2 under buffered (pH 7) conditions

An effective oxidative protocol for the liberation of ketones from SAMP hydrazones employing peroxyselenous acid under aqueous buffered conditions (pH 7) has been developed. The procedure proceeds without epimerization of adjacent stereocenters or dehydration, in representative SAMP alkylation and aldol reaction adducts, respectively.

Acid Catalyzed Alcoholysis of an Epoxide and Reactions of Products on Contact with Silica Gel

The alcoholysis of epoxide 1 in acidic methanol leads to various products; one of these - hydroxymethoxyketone 7 - rearranges to the isomeric ketone 14 on contact with silica gel. Keywords: Cleavage of Epoxide, Rearrangement