13799-94-5

Basic information

• Product Name: Dicyclohexylnitroxyl
• CAS NO: 13799-94-5
• Molecular Weight: 196.313
• Mol File: 13799-94-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Dicyclohexylnitroxyl(CAS DataBase Reference)
• NIST Chemistry Reference: Dicyclohexylnitroxyl(13799-94-5)
• EPA Substance Registry System: Dicyclohexylnitroxyl(13799-94-5)

Safety Data

• Hazardous Substances Data: 13799-94-5(Hazardous Substances Data)

Upstream product

• 110-82-7 cyclohexane 
• 947-92-2 N-nitrosodicyclohexylamine 

Relevant articles and documents

ESR Studies of Nitroxide Radicals Formed in the Low Temperature Photolysis of N-Nitrosamines

Various N-nitrosamines were photolyzed in toluene solution in the temperature range -100 edg C to -30 deg C to yield dialkyl nitroxides.The nitrosamines studied were N-nitrosodimethylamine, N-nitrosodiethylamine, N-nitrosodipropylamine, N-nitrosodibutylamine and N-nitrosodicyclohexylamine.Subsequent nitroxide side products were also detected by ESR, and a mechanism for their formation is proposed.Temperature dependent hyperfine couplings of the methylene protons were observed for a few radicals of the type R1-CH2-NO-R2 radicals.

SPIN TRAPPING REACTIONS WITH NITRIC OXYDES, I. DIALKYL NITROXYDES

Dialkyl-nitroxide radicals formed from nitric oxyde, wich trapped two alkyl radicals in consecutive steps, have been detected by Electron Spin Resonance spectroscopy.The structure of radicals was found independent of the way of alkyl radical generation.Stereoselectivity of radical trapping was observed for secondary alkyl radicals with chiral carbons.