1380402-86-7

Basic information

• Product Name: 4-methyl-N-((E)-3-(thiophen-2-yl)-1-(p-tolyl)allylidene)benzenesulfonamide
• Synonyms: 4-methyl-N-((E)-3-(thiophen-2-yl)-1-(p-tolyl)allylidene)benzenesulfonamide
• CAS NO: 1380402-86-7
• Molecular Weight: 381.519
• Mol File: 1380402-86-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-methyl-N-((E)-3-(thiophen-2-yl)-1-(p-tolyl)allylidene)benzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methyl-N-((E)-3-(thiophen-2-yl)-1-(p-tolyl)allylidene)benzenesulfonamide(1380402-86-7)
• EPA Substance Registry System: 4-methyl-N-((E)-3-(thiophen-2-yl)-1-(p-tolyl)allylidene)benzenesulfonamide(1380402-86-7)

Safety Data

• Hazardous Substances Data: 1380402-86-7(Hazardous Substances Data)

Upstream product

• 70-55-3 toluene-4-sulfonamide 
• 6028-89-3 (E)-3-thiophen-2-yl-1-p-tolylpropenone 

Downstream Products

• 1380402-72-1 (3R,4R)-3-phenyl-4-(thiophen-2-yl)-6-(p-tolyl)-1-tosyl-3,4-dihydropyridin-2(1H)-one 

Relevant articles and documents

Dihydropyridones: Catalytic asymmetric synthesis, N- to C-sulfonyl transfer, and derivatizations

Benzotetramisole (1) promotes the reaction of ammonium enolates derived from arylacetic acids with N-tosyl-α,β-unsaturated ketimines, thus giving dihydropyridones with high diastereo- and enantiocontrol (see scheme). These products readily undergo N- to C-sulfonyl photoisomerization and are derivatized to afford stereodefined piperidines and tetrahydropyrans.