138240-07-0Relevant articles and documents
Aerobic Oxygenation of Olefinic Compounds into the Corresponding α-Hydroxy Ketones Using the Catalyst System of OsO4 and Ni(II) Complex
Takai, Toshihiro,Yamada, Tohru,Mukaiyama, Teruaki
, p. 1499 - 1502 (1991)
In the presence of the catalyst system of OsO4 and bis(3-methyl-2,4-pentanedionato)nickel(II), various olefinic compounds are directly converted into the corresponding α-hydroxy ketones in good yields with molecular oxygen and an aldehyde.
Regiochemistry of Boron Trifluoride Mediated Hydrolysis of Glycidyl Benzoates
Yoshitake, Makoto,Kobayashi, Hiroyuki,Yamamoto, Makoto,Kohmoto, Shigeo,Yamada, Kazutoshi
, p. 1865 - 1868 (2007/10/02)
Hydrolysis of glycidyl benzoates in the presence of BF3*OEt2 in CH2Cl2 affords regioisomeric triol monobenzoates, their ratios remarkably change depending on the temperature particularly in the reaction of 3,3-dimethylglycidyl benzoate.