138298-52-9

Basic information

• Product Name: (E)-1-((1S,5S,7R)-10,10-Dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-3-(3-methoxy-phenyl)-propenone
• Synonyms: (E)-1-((1S,5S,7R)-10,10-Dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-3-(3-methoxy-phenyl)-propenone
• CAS NO: 138298-52-9
• Molecular Weight: 375.489
• Mol File: 138298-52-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-((1S,5S,7R)-10,10-Dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-3-(3-methoxy-phenyl)-propenone(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-((1S,5S,7R)-10,10-Dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-3-(3-methoxy-phenyl)-propenone(138298-52-9)
• EPA Substance Registry System: (E)-1-((1S,5S,7R)-10,10-Dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-3-(3-methoxy-phenyl)-propenone(138298-52-9)

Safety Data

• Hazardous Substances Data: 138298-52-9(Hazardous Substances Data)

Upstream product

• 15851-92-0 (E)-3-methoxycinnamoyl chloride 
• 195877-76-0 Bornane<10,2>sultam 
• 6099-04-3 trans-3-methoxycinnamic acid 

Downstream Products

• 110901-90-1 (1R,2R)-2-(3-methoxyphenyl)cyclopropanecarboxylic acid 
• 138298-59-6 ((1S,5S,7R)-10,10-Dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-[(1R,2R)-2-(3-methoxy-phenyl)-cyclopropyl]-methanone 

Relevant articles and documents

Stereoselective palladium-catalyzed cyclopropanation of α,β-unsaturated carboxylic acids derivatized with Oppolzer's sultam

N-enoyl sultans, derived from α,β-unsaturated carboxylic acids and bornane[10,2]sultam, undergo a stereoselective Pd-catalyzed cyclopropanation upon treatment with diazomethane. The stereoselectivity of the reaction is temperature dependent.