138336-93-3

Basic information

• Product Name: 4-(methylsulfanyl)-2-{3-[4-(methylsulfanyl)-2',6-bipyridin-2-yl]phenyl}-2',6-bipyridine
• Synonyms: 4-(methylsulfanyl)-2-{3-[4-(methylsulfanyl)-2',6-bipyridin-2-yl]phenyl}-2',6-bipyridine
• CAS NO: 138336-93-3
• Molecular Formula: C₂₈H₂₂N₄S₂
• Molecular Weight: 478.63108
• Mol File: 138336-93-3.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-(methylsulfanyl)-2-{3-[4-(methylsulfanyl)-2',6-bipyridin-2-yl]phenyl}-2',6-bipyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(methylsulfanyl)-2-{3-[4-(methylsulfanyl)-2',6-bipyridin-2-yl]phenyl}-2',6-bipyridine(138336-93-3)
• EPA Substance Registry System: 4-(methylsulfanyl)-2-{3-[4-(methylsulfanyl)-2',6-bipyridin-2-yl]phenyl}-2',6-bipyridine(138336-93-3)

Safety Data

• Hazardous Substances Data: 138336-93-3(Hazardous Substances Data)

Upstream product

• 1122-62-9 2-acetylpyridine 
• 6781-42-6 1,3-diacetylbenzene 
• 78570-34-0 3,3-bis(methylsulfanyl)-1-pyridin-2-ylprop-2-en-1-one 

Downstream Products

• 138336-94-4 1,3-bis-(2,2'-bipyridin-6-yl)benzene 

Relevant articles and documents

Dinuclear Double Helicates incorporating a 1,3-Phenylene Spacer; the Crystal and Molecular Structure of Diacetato-1κ2O-,2κ2O-bis2N,N':2κ2N'',N'''>dinickel Bis(hexafluorophosphate)

Linking two bipyridine units by a 1,3-phenylene spacer has provided a novel class of ligand which promotes the spontaneous self-assembly of double helicates upon reaction with transition-metal ions.Interaction with copper(I) or silver(I) resulted in dinuclear double-helical complexes with the metal ions occupying pseudo-tetrahedral co-ordination sites.Reaction with cobalt(II) or nickel(II) acetates gave similar dinuclear double-helical structures with a didentate acetate ligand completing the co-ordination sphere of each metal to give a pseudo-octahedral geometry.The crystal structure of 22(O2CMe)2>2 2 = 1,3-bis(4-meth ylthio-2,2'-bipyridin-6-yl)benzene> has been determined.The two metal centres are separated by 5.875 Angstroem.In contrast to the helicates formed by the linear oligopyridines, no significant ?-stacking interactions are observed between pyridine moieties on the helical strands.

α,α'-Oligopyridines: A Source of New Materials

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