138346-24-4

Basic information

• Product Name: {Ru(CH₃C₆H₄CH(CH₃)2)Cl₂(NC₅H₄NHC₆H₅)}
• Synonyms: {Ru(CH₃C₆H₄CH(CH₃)2)Cl₂(NC₅H₄NHC₆H₅)}
• CAS NO: 138346-24-4
• Molecular Weight: 476.411
• Mol File: 138346-24-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {Ru(CH₃C₆H₄CH(CH₃)2)Cl₂(NC₅H₄NHC₆H₅)}(CAS DataBase Reference)
• NIST Chemistry Reference: {Ru(CH₃C₆H₄CH(CH₃)2)Cl₂(NC₅H₄NHC₆H₅)}(138346-24-4)
• EPA Substance Registry System: {Ru(CH₃C₆H₄CH(CH₃)2)Cl₂(NC₅H₄NHC₆H₅)}(138346-24-4)

Safety Data

• Hazardous Substances Data: 138346-24-4(Hazardous Substances Data)

Upstream product

• 52462-29-0 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 
• 6631-37-4 2-(phenylamino)pyridine 
• 128706-72-9 [Ru(p-cymene)Cl₂]2 

Relevant articles and documents

Ruthenium-Catalyzed Remote C-H Sulfonylation of N-Aryl-2-aminopyridines with Aromatic Sulfonyl Chlorides

A ruthenium-catalyzed remote sulfonylation at the C5 position of the pyridine group of N-aryl-2-aminopyridines with aromatic sulfonyl chlorides is described. The mechanistic and deuterium labeling studies clearly reveal that the ruthenametallacycle is a key intermediate in the reaction, which forms via the C-H bond activation. The DFT calculation supports that the C5 position of the 2-aminopyridine group carries a more negative charge (-0.304) as compared with other carbons in the metalacycle intermediate.