13837-67-7

Basic information

• Product Name: [1R,3R,(+)]-1-Methyl-3-isopropylcyclohexane
• Synonyms: [1R,3R,(+)]-1-Methyl-3-isopropylcyclohexane;[1R,3R,(+)]-m-Menthane
• CAS NO: 13837-67-7
• Molecular Formula: C₁₀H₂₀
• Molecular Weight: 0
• Mol File: 13837-67-7.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: [1R,3R,(+)]-1-Methyl-3-isopropylcyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: [1R,3R,(+)]-1-Methyl-3-isopropylcyclohexane(13837-67-7)
• EPA Substance Registry System: [1R,3R,(+)]-1-Methyl-3-isopropylcyclohexane(13837-67-7)

Safety Data

• Hazardous Substances Data: 13837-67-7(Hazardous Substances Data)

Usage

Description

[1R,3R,(+)]-1-Methyl-3-isopropylcyclohexane is a chiral chemical compound belonging to the cycloalkanes family, characterized by a molecular formula of C10H20. It features a cyclohexane ring with a 1-methyl-3-isopropyl group attached, which endows it with unique structural properties. These properties make it a valuable building block in organic synthesis for creating more complex organic molecules.

Uses

Used in Organic Synthesis:
[1R,3R,(+)]-1-Methyl-3-isopropylcyclohexane is used as a building block in the field of organic synthesis for its unique structure that can serve as a starting point for the creation of more complex organic molecules. Its chiral nature allows for the development of various enantiomers, which can have different biological activities and applications.
Used in Fragrance and Flavor Industries:
In the fragrance and flavor industries, [1R,3R,(+)]-1-Methyl-3-isopropylcyclohexane is used as an additive to contribute to the scent or taste of various products. Its distinct chemical structure can provide specific olfactory or gustatory characteristics, enhancing the sensory experience of consumer goods.

Upstream product

• 13837-95-1 1(7),8-m-Menthadien, β-Silvestren 
• 13828-31-4 (-)-Dihydro-sylvestren 
• 13837-70-2 (3R)-(+)-m-Menth-1⁽⁶⁾-en 
• 5208-51-5 trans-(-)-5methyl3(1methylethenyl)cyclohexene 
• 83289-55-8 (1S,3R)-(-)-trans-m-Menth-5-en 
• 83224-04-8 Acetic acid (1S,2S,4R)-4-isopropyl-2-methyl-cyclohexyl ester 
• 83224-12-8 Acetic acid (1R,2S,4R)-4-isopropyl-2-methyl-cyclohexyl ester 
• 4497-93-2 'd-Silvestrene-dihydrochloride' 
• 499-03-6 (3R)-(+)-Sylvestren 
• 22625-86-1 m-menth-6-en-8-ol 
• 85392-39-8 (1S,3S,4R,6R)-4-Acetoxy-caran 
• 1461-27-4 1-methyl-5-(1-methylethenyl)-(R)-cyclohexene 
• 13837-69-9 (+)(1R:3R)-m-Menthan-trans-1-ol-acetat 
• 67-56-1 methanol 

Relevant articles and documents

Study on selectivity of β-myrcene hydrogenation in high-pressure carbon dioxide catalysed by noble metal catalysts

Hydrogenation of monoterpenes, such as β-myrcene, in high-density carbon dioxide over 0.5 wt.% Pd, or Rh, or Ru supported on alumina was investigated. Hydrogenation catalysed by Rh and Ru is generally faster in a single supercritical (sc) phase (gaseous reagents and solid catalyst) than in a biphasic system (liquid + gas reactants + solid catalyst). The reaction catalysed by Pd occurs faster in two phases. The final composition of the reaction mixture is strongly dependent on the noble metal catalyst used for the reaction. Palladium gives mainly 2,6-dimethyloctane (≈95%), rhodium produces 2,6-dimethyloctane with a yield higher than 40%, and around 40% of 2,6-dimethyloct-2-ene, while ruthenium gives around 10% of 2,6-dimethyloctane and 50% of 2,6-dimethyloct-2-ene leaving the highest amount of unreacted β-myrcene. The Pd catalyst is highly active with an excellent selectivity in enabling the one-pot synthesis of 2,6-dimethyloctane through β-myrcene hydrogenation in the presence of scCO2. The overall activity of the noble metal catalysts decreased in the order Pd > Rh > Ru. The problem of leaching of the active metal from the catalyst rod was also investigated. The Royal Society of Chemistry 2009.

STABLE CARBOCATIONS FROM TERPENOIDS. IV. GENERATION OF STABLE IONS FROM SOME MONOTERPENES OF THE MENTAHNE AND CARANE SERIES

Stable carbocations were generated for the first time from momoterpenes of the menthane and carane-dipentene series, terpinolene, α and γ-terpinenes, isomeric p-menthenes, cis- and trans-caranes, and silvestrene.Their structures, reactions with nucleophiles, and certain rearrangements were studied.Differences were noted in the reactivity of the substrates in superacids and under conditions of acid catalysis