138373-08-7Relevant articles and documents
Sulfonyl esters 6. Elucidation of the first sequence in the Trithioorthoformate reaction
Baum, James Clayton,Black, Bradley Eugene,Precedo, Laura,Goehl, John Edward,Langler, Richard Francis
, p. 444 - 452 (2007/10/02)
The one-pot conversion of a mercaptan and an aryl methanesulfonate into a trithioorthoformate is described.The intermediacy of a sulfide-sulfonate ester is firmly established.Experimental and computational results permit the formulation of a possible pathway for the formation of the intermediate sulfide-sulfonate ester.Key words: single electron transfer, sulfonate esters, sulfide-sulfonate esters.