1384108-66-0

Basic information

• Product Name: C₆H₉O₄S^(1-)*Na⁽¹⁺⁾
• Synonyms: C₆H₉O₄S^(1-)*Na⁽¹⁺⁾
• CAS NO: 1384108-66-0
• Molecular Weight: 200.191
• Mol File: 1384108-66-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₆H₉O₄S^(1-)*Na⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: C₆H₉O₄S^(1-)*Na⁽¹⁺⁾(1384108-66-0)
• EPA Substance Registry System: C₆H₉O₄S^(1-)*Na⁽¹⁺⁾(1384108-66-0)

Safety Data

• Hazardous Substances Data: 1384108-66-0(Hazardous Substances Data)

Upstream product

• 112780-08-2 hex-3-yn-2-ol 
• 1384108-48-8 C₆H₉O₄S^(1-)*Na⁽¹⁺⁾ 

Relevant articles and documents

The substrate spectrum of the inverting sec-alkylsulfatase Pisa1

The substrate spectrum of the inverting alkylsulfatase Pisa1 was investigated using a range of sec-alkyl sulfate esters bearing aromatic, olefinic and acetylenic moieties. Perfect enantioselectivities were obtained for substrates bearing groups of different size adjacent to the sulfate ester moiety. Insufficient selectivities could be doubled by using dimethyl sulfoxide (DMSO) as co-solvent. Hydrolytically unstable benzylic sulfate esters could be sufficiently stabilised by introduction of electron-withdrawing substituents. Overall, Pisa1 appears to be a very useful inverting alkylsulfatase for the deracemisation of rac-sec-alcohols via enzymatic hydrolysis of their corresponding sulfate esters, which furnishes homochiral products possessing the 'anti-Kazlauskas' configuration. Copyright