138445-32-6

Basic information

• Product Name: 1-phenyl-1-(4,4,4-trifluoro-1-iodobutyl)silacyclobutane
• Synonyms: 1-phenyl-1-(4,4,4-trifluoro-1-iodobutyl)silacyclobutane
• CAS NO: 138445-32-6
• Molecular Weight: 384.255
• Mol File: 138445-32-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-phenyl-1-(4,4,4-trifluoro-1-iodobutyl)silacyclobutane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-1-(4,4,4-trifluoro-1-iodobutyl)silacyclobutane(138445-32-6)
• EPA Substance Registry System: 1-phenyl-1-(4,4,4-trifluoro-1-iodobutyl)silacyclobutane(138445-32-6)

Safety Data

• Hazardous Substances Data: 138445-32-6(Hazardous Substances Data)

Upstream product

• 3401-28-3 1-chloro-1-phenyl-1-silacyclobutane 
• 3401-26-1 dichloro(3-chloropropyl)phenylsilane 
• 353-83-3 1,1,1-trifluoro-2-iodoethane 
• 74045-43-5 1-phenyl-1-vinyl-1-silacyclobutane 

Relevant articles and documents

Nucleophile-induced ring enlargement of 1-(1-iodoalkyl)silacyclobutane and 1-(1,2-epoxyalkyl)silacyclobutane into silacyclopentane. Application to the synthesis of 1,4-diol, 4-alken-1-ol, and 1,4,5-triol

Two methods for ring enlargement of silacyclobutane into silacyclopentane have been described. (1) Treatment of 1-(1-iodoalkyl)silacyclobutane with t-BuOK or AgOAc provided 2-alkyl-1-silacyclopentanes which were easily converted into 1,4-diols by oxidativ