138457-80-4

Basic information

• Product Name: <1R,1α(S^*),3α(E)>-1-Cyano-1-(3-phenoxyphenyl)methyl 2,2-Dimethyl-3-<3-tert-butoxy-2-(phenylsulfonyl)-3-oxo-1-propenyl>cyclopropanecarboxylate
• Synonyms: <1R,1α(S^*),3α(E)>-1-Cyano-1-(3-phenoxyphenyl)methyl 2,2-Dimethyl-3-<3-tert-butoxy-2-(phenylsulfonyl)-3-oxo-1-propenyl>cyclopropanecarboxylate
• CAS NO: 138457-80-4
• Molecular Weight: 587.694
• Mol File: 138457-80-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: <1R,1α(S^*),3α(E)>-1-Cyano-1-(3-phenoxyphenyl)methyl 2,2-Dimethyl-3-<3-tert-butoxy-2-(phenylsulfonyl)-3-oxo-1-propenyl>cyclopropanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: <1R,1α(S^*),3α(E)>-1-Cyano-1-(3-phenoxyphenyl)methyl 2,2-Dimethyl-3-<3-tert-butoxy-2-(phenylsulfonyl)-3-oxo-1-propenyl>cyclopropanecarboxylate(138457-80-4)
• EPA Substance Registry System: <1R,1α(S^*),3α(E)>-1-Cyano-1-(3-phenoxyphenyl)methyl 2,2-Dimethyl-3-<3-tert-butoxy-2-(phenylsulfonyl)-3-oxo-1-propenyl>cyclopropanecarboxylate(138457-80-4)

Safety Data

• Hazardous Substances Data: 138457-80-4(Hazardous Substances Data)

Upstream product

• 138336-34-2 (1R,1α,3α)-6,6-Dimethyl-4-<2-tert-butoxy-2-oxo-1-(phenylsulfonyl)ethyl>-3-oxabicyclo<3.1.0>hexan-2-one 
• 39515-47-4 (S)-m-phenoxybenzaldehyde cyanohydrin 
• 5292-43-3 bromoacetic acid tert-butyl ester 
• 63006-68-8 tert-butyl (phenylthio)acetate 
• 138336-33-1 tert-Butyl 2-(Phenylsulfonyl)acetate 
• 108-98-5 thiophenol 

Relevant articles and documents

A New Way toward Z α,β Unsaturated Esters: A Pyrethroid Application

Use of the stereospecific condensation of β carbalkoxysulfones with aldehydes, followed by the stereospecific reduction of the afforded sulfonyl acrylate with sodium dithionite allows us to propose this method as a new way to prepare Z α,β unsaturated esters.Steric hindrance seems to be the reason for the selectivity of the reduction and the mechanism was proved, by X-ray of an intermediate, to be a cis Michael addition of HSO2-, followed by an anti elimination of SO2 and the sulfinate group.This method discovered in the pyrethroid series for the synthesis of acrinathrin 1 could have general application.