13847-65-9 Usage
Description
Trifluoroamine oxide, also known as perfluorinated amine, is a colorless, mobile liquid or gas obtained through the fluorination of nitrosyl fluoride using UV light, high temperature, or pressure. An alternative process involves burning nitric oxide and fluorine, followed by rapidly quenching the gaseous mixture as it leaves the flame zone. It possesses unique chemical properties, including a heat of vaporization of 3170 cal/mole and a critical temperature of 36°C.
Uses
Used in Organic Synthesis:
Trifluoroamine oxide is used as a reagent in organic synthesis for its ability to facilitate various chemical reactions and improve the efficiency of the synthesis process.
Used in Oxidizer Applications:
In the aerospace industry, trifluoroamine oxide is used as an oxidizer in fuels for rockets and missiles. Its properties make it a suitable candidate for enhancing the performance and efficiency of these propulsion systems.
Used in Pharmaceutical Industry:
Trifluoroamine oxide can be used as a building block or intermediate in the synthesis of various pharmaceutical compounds, contributing to the development of new drugs and therapies.
Used in Environmental Applications:
Due to its unique chemical properties, trifluoroamine oxide may be utilized in environmental applications, such as in the treatment of contaminated water or air, where it can help break down or neutralize harmful substances.
Used in Chemical Research:
Trifluoroamine oxide can be employed as a research tool in the study of perfluorinated compounds and their interactions with other molecules, providing valuable insights into their behavior and potential applications.
Hazard
Explodes on contact with reducing agents
and at high pressures. Irritant.
Safety Profile
Poison by inhalation
and intraperitoneal routes. A skin, eye, and
mucous membrane irritant. When heated to
decomposition it emits very toxic fumes of
Fand NOx. See also FLUORIDES.
Check Digit Verification of cas no
The CAS Registry Mumber 13847-65-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,8,4 and 7 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 13847-65:
(7*1)+(6*3)+(5*8)+(4*4)+(3*7)+(2*6)+(1*5)=119
119 % 10 = 9
So 13847-65-9 is a valid CAS Registry Number.
InChI:InChI=1/F3NO/c1-4(2,3)5
13847-65-9Relevant articles and documents
Endothermic formation of a chemical bond by entropic stabilization: Difluoronitroxide radical in solid argon
Misochko, Eugenii Ya.,Akimov, Alexander V.,Goldschleger, Ilya U.,Boldyrev, Alexander I.,Wight, Charles A.
, p. 405 - 410 (2007/10/03)
Difluoronitroxide radical (F2NO) has been formed in solid argon matrices by successive addition of two diffusing F atoms to NO. This radical exists in dynamic equilibrium with a van der Waals complex (FFNO). Measurements of the equilibrium concentrations as a function of temperature show that the changes in enthalpy and the entropy associated with formation of the F2NO radical are ΔH = 1240 ± 180 J/mol and ΔS = 62 ± 10 J/(mol K). Because both these quantities are positive, the equilibrium favors F2NO only at elevated temperatures. This situation is a rare case in which formation of a chemical bond is stabilized only by an increase in the entropy of the system.
