138541-58-9Relevant articles and documents
Metal Complexes in Inorganic Matrices, 8. - Chromium Tricarbonyl Complexes of Benzoylacetonate-Substituted Titanium-, Zirconium-, and Aluminium Alkoxides
Schubert, Ulrich,Buhler, Hermann,Hirle, Brigitte
, p. 999 - 1004 (2007/10/02)
Benzoylacetone (bzac-H) reacts with one equivalent of Al(OtBu)3 or Zr(OPr)4 to give the mono-substituted compounds (bzac)Al(OtBu)2 (1b) and (bzac)Zr(OPr)3 (1a), while with one equivalent of Ti(OtBu)4 or Zr(OtBu)4 the bis-substituted derivatives (bzac)2Ti(OtBu)2 (3c) and (bzac)2Zr(OtBu)2 (3d) are obtained.Upon heating in dibutyl ether, 1b disproportionates into (bzac)2Al(OtBu) (3b) and Al(OtBu)3.Thermal reaction of 1a, 3b, and 3c with Cr(CO)6 leads to metal complexes having a Cr(CO)3 moiety ?-bonded to the phenyl group of the benzoylacetonate ligand.Key Words: β-Diketonates / Metal alkoxides / Sol-gel chemistry / ?-Arene complexes / Chromium complexes