138625-62-4

Basic information

• Product Name: Benzamide, N-(1-formylethenyl)-
• Synonyms: Benzamide, N-(1-formylethenyl)-
• CAS NO: 138625-62-4
• Molecular Formula: C₁₀H₉NO₂
• Molecular Weight: 0
• Mol File: 138625-62-4.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzamide, N-(1-formylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, N-(1-formylethenyl)-(138625-62-4)
• EPA Substance Registry System: Benzamide, N-(1-formylethenyl)-(138625-62-4)

Safety Data

• Hazardous Substances Data: 138625-62-4(Hazardous Substances Data)

Upstream product

• 75-09-2 dichloromethane 
• 10283-95-1 N-allylbenzamide 
• 138625-63-5 N-[2-hydroxy-1-(hydroxymethyl)ethyl]benzamide 
• 74-95-3 1,1-dibromomethane 
• 98-88-4 benzoyl chloride 

Downstream Products

• 146759-95-7 N-(1-benzyl-4-methylhexahydro-1H-1,4-diazepine-6-yl)benzamide 
• 1176846-78-8 (S)-(+)-N-(1-formyl-3,4-dimethylcyclohex-3-enyl)benzamide 

Relevant articles and documents

Preparation of α-Substituted Acroleins via the Reaction of Aldehyde with Dihalomethane and Diethylamine

Treatment of ozonides or aldehydes with a mixture of dihalomethane and diethylamine in dichloromethane affords α-substituted acroleins in good yields, the β-carbon of the acrolein being derived from dihalomethane; the relative rates and yields are in the following order: CH2I2 > CH2Br2 > CH2Cl2.

An efficient synthesis of 6-substituted aminohexahydro-1H-1,4-diazepines from 2-substituted aminopropenals

Swern oxidation of 2-substituted amino-1,3-propanediols 20a - d, 38, 41, and 42 smoothly proceeded to give the oxidative dehydration products, 2-substituted aminopropenals 17a - d, 43, 45 and 46, respectively. Reaction of the intriguing 2-substituted amin